The thickness of the atmosphere is about 120 km from the Earth's surface. The total mass of air in the atmosphere is (5.1-5.3) 10 18 kg. Of these, the mass of dry air is 5.1352 ± 0.0003 10 18 kg, the total mass of water vapor is on average 1.27 10 16 kg.

tropopause

The transitional layer from the troposphere to the stratosphere, the layer of the atmosphere in which the decrease in temperature with height stops.

Stratosphere

The layer of the atmosphere located at an altitude of 11 to 50 km. A slight change in temperature in the 11-25 km layer (lower layer of the stratosphere) and its increase in the 25-40 km layer from −56.5 to 0.8 ° (upper stratosphere or inversion region) are typical. Having reached a value of about 273 K (almost 0 °C) at an altitude of about 40 km, the temperature remains constant up to an altitude of about 55 km. This region of constant temperature is called the stratopause and is the boundary between the stratosphere and the mesosphere.

Stratopause

The boundary layer of the atmosphere between the stratosphere and the mesosphere. There is a maximum in the vertical temperature distribution (about 0 °C).

Mesosphere

Earth's atmosphere

Earth's atmosphere boundary

Thermosphere

The upper limit is about 800 km. The temperature rises to altitudes of 200-300 km, where it reaches values ​​of the order of 1500 K, after which it remains almost constant up to high altitudes. Under the influence of ultraviolet and x-ray solar radiation and cosmic radiation, air is ionized ("polar lights") - the main regions of the ionosphere lie inside the thermosphere. At altitudes above 300 km, atomic oxygen predominates. The upper limit of the thermosphere is largely determined by the current activity of the Sun. During periods of low activity - for example, in 2008-2009 - there is a noticeable decrease in the size of this layer.

Thermopause

The region of the atmosphere above the thermosphere. In this region, the absorption of solar radiation is insignificant and the temperature does not actually change with height.

Exosphere (scattering sphere)

Up to a height of 100 km, the atmosphere is a homogeneous, well-mixed mixture of gases. In more high layers the distribution of gases in height depends on their molecular masses, the concentration of heavier gases decreases faster with distance from the Earth's surface. Due to the decrease in gas density, the temperature drops from 0 °C in the stratosphere to −110 °C in the mesosphere. However, the kinetic energy of individual particles at altitudes of 200–250 km corresponds to a temperature of ~150 °C. Above 200 km, significant fluctuations in temperature and gas density are observed in time and space.

At an altitude of about 2000-3500 km, the exosphere gradually passes into the so-called near space vacuum, which is filled with highly rarefied particles of interplanetary gas, mainly hydrogen atoms. But this gas is only part of the interplanetary matter. The other part is composed of dust-like particles of cometary and meteoric origin. In addition to extremely rarefied dust-like particles, electromagnetic and corpuscular radiation of solar and galactic origin penetrates into this space.

The troposphere accounts for about 80% of the mass of the atmosphere, the stratosphere accounts for about 20%; the mass of the mesosphere is no more than 0.3%, the thermosphere is less than 0.05% of the total mass of the atmosphere. Based on the electrical properties in the atmosphere, the neutrosphere and ionosphere are distinguished. It is currently believed that the atmosphere extends to an altitude of 2000-3000 km.

Depending on the composition of the gas in the atmosphere, they emit homosphere and heterosphere. heterosphere- this is an area where gravity affects the separation of gases, since their mixing at such a height is negligible. Hence follows the variable composition of the heterosphere. Below it lies a well-mixed, homogeneous part of the atmosphere, called the homosphere. The boundary between these layers is called turbopause, it lies at an altitude of about 120 km.

Physiological and other properties of the atmosphere

Already at an altitude of 5 km above sea level, an untrained person develops oxygen starvation and, without adaptation, a person's performance is significantly reduced. This is where the physiological zone of the atmosphere ends. Human breathing becomes impossible at an altitude of 9 km, although up to about 115 km the atmosphere contains oxygen.

The atmosphere provides us with the oxygen we need to breathe. However, due to the drop in the total pressure of the atmosphere as you rise to a height, the partial pressure of oxygen also decreases accordingly.

In rarefied layers of air, the propagation of sound is impossible. Up to altitudes of 60-90 km, it is still possible to use air resistance and lift for controlled aerodynamic flight. But starting from altitudes of 100-130 km, the concepts of the M number and the sound barrier familiar to every pilot lose their meaning: there passes the conditional Karman line, beyond which the area of ​​\u200b\u200bpurely ballistic flight begins, which can only be controlled using reactive forces.

At altitudes above 100 km, the atmosphere is also deprived of another remarkable property - the ability to absorb, conduct and transfer thermal energy by convection (i.e., by means of air mixing). This means that various elements of equipment, equipment of the orbital space station will not be able to be cooled from the outside in the way it is usually done on an airplane - with the help of air jets and air radiators. At such a height, as in space in general, the only way to transfer heat is thermal radiation.

History of the formation of the atmosphere

According to the most common theory, the Earth's atmosphere has been in three different compositions over time. Initially, it consisted of light gases (hydrogen and helium) captured from interplanetary space. This so-called primary atmosphere(about four billion years ago). At the next stage, active volcanic activity led to the saturation of the atmosphere with gases other than hydrogen (carbon dioxide, ammonia, water vapor). This is how secondary atmosphere(about three billion years before our days). This atmosphere was restorative. Further, the process of formation of the atmosphere was determined by the following factors:

• leakage of light gases (hydrogen and helium) into interplanetary space;
• chemical reactions occurring in the atmosphere under the influence of ultraviolet radiation, lightning discharges and some other factors.

Gradually, these factors led to the formation tertiary atmosphere, characterized by a much lower content of hydrogen and a much higher content of nitrogen and carbon dioxide (formed as a result of chemical reactions from ammonia and hydrocarbons).

Nitrogen

The formation of a large amount of nitrogen N 2 is due to the oxidation of the ammonia-hydrogen atmosphere by molecular oxygen O 2, which began to come from the surface of the planet as a result of photosynthesis, starting from 3 billion years ago. Nitrogen N 2 is also released into the atmosphere as a result of the denitrification of nitrates and other nitrogen-containing compounds. Nitrogen is oxidized by ozone to NO in the upper atmosphere.

Nitrogen N 2 enters into reactions only under specific conditions (for example, during a lightning discharge). Oxidation of molecular nitrogen by ozone during electrical discharges is used in small quantities in the industrial production of nitrogen fertilizers. It can be oxidized with low energy consumption and converted into a biologically active form by cyanobacteria (blue-green algae) and nodule bacteria that form rhizobial symbiosis with legumes, the so-called. green manure.

Oxygen

The composition of the atmosphere began to change radically with the advent of living organisms on Earth, as a result of photosynthesis, accompanied by the release of oxygen and the absorption of carbon dioxide. Initially, oxygen was spent on the oxidation of reduced compounds - ammonia, hydrocarbons, the ferrous form of iron contained in the oceans, etc. At the end of this stage, the oxygen content in the atmosphere began to grow. Gradually, a modern atmosphere with oxidizing properties formed. Since this caused serious and abrupt changes in many processes occurring in the atmosphere, lithosphere and biosphere, this event was called the Oxygen catastrophe.

noble gases

Air pollution

AT recent times man began to influence the evolution of the atmosphere. The result of his activities was a constant significant increase in the content of carbon dioxide in the atmosphere due to the combustion of hydrocarbon fuels accumulated in previous geological epochs. Huge amounts of CO 2 are consumed during photosynthesis and absorbed by the world's oceans. This gas enters the atmosphere due to the decomposition of carbonate rocks and organic substances of plant and animal origin, as well as due to volcanism and human production activities. Over the past 100 years, the content of CO 2 in the atmosphere has increased by 10%, with the main part (360 billion tons) coming from fuel combustion. If the growth rate of fuel combustion continues, then in the next 200-300 years the amount of CO 2 in the atmosphere will double and may lead to global climate change.

Fuel combustion is the main source of polluting gases (СО,, SO 2). Sulfur dioxide is oxidized by atmospheric oxygen to SO 3 in the upper atmosphere, which in turn interacts with water vapor and ammonia, and the resulting sulfuric acid (H 2 SO 4) and ammonium sulfate ((NH 4) 2 SO 4) return to the surface of the Earth in the form of a so-called. acid rain. The use of internal combustion engines leads to significant air pollution with nitrogen oxides, hydrocarbons and lead compounds (tetraethyl lead Pb (CH 3 CH 2) 4)).

Aerosol pollution of the atmosphere is caused both by natural causes (volcanic eruption, dust storms, entrainment of sea water droplets and plant pollen, etc.) and by human economic activity (mining of ores and building materials, fuel combustion, cement production, etc.). Intense large-scale removal of solid particles into the atmosphere is one of the possible causes of climate change on the planet.

see also

• Jacchia (atmosphere model)

Notes

Links

Literature

1. V. V. Parin, F. P. Kosmolinsky, B. A. Dushkov"Space biology and medicine" (2nd edition, revised and supplemented), M .: "Prosveshchenie", 1975, 223 pages.
2. N. V. Gusakova"Chemistry of the environment", Rostov-on-Don: Phoenix, 2004, 192 with ISBN 5-222-05386-5
3. Sokolov V. A. Geochemistry of natural gases, M., 1971;
4. McEwen M, Phillips L. Chemistry of the atmosphere, M., 1978;
5. Wark K., Warner S. Air pollution. Sources and control, trans. from English, M.. 1980;
6. Monitoring of background pollution of natural environments. in. 1, L., 1982.

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Atmosphere(from the Greek atmos - steam and spharia - ball) - the air shell of the Earth, rotating with it. The development of the atmosphere was closely connected with the geological and geochemical processes taking place on our planet, as well as with the activities of living organisms.

The lower boundary of the atmosphere coincides with the surface of the Earth, since air penetrates into the smallest pores in the soil and is dissolved even in water.

The upper limit at an altitude of 2000-3000 km gradually passes into outer space.

Oxygen-rich atmosphere makes life possible on Earth. Atmospheric oxygen is used in the process of breathing by humans, animals, and plants.

If there were no atmosphere, the Earth would be as quiet as the moon. After all, sound is the vibration of air particles. The blue color of the sky is explained by the fact that the sun's rays, passing through the atmosphere, as if through a lens, are decomposed into their component colors. In this case, the rays of blue and blue colors are scattered most of all.

The atmosphere retains most of the ultraviolet radiation from the Sun, which has a detrimental effect on living organisms. It also keeps heat at the surface of the Earth, preventing our planet from cooling.

The structure of the atmosphere

Several layers can be distinguished in the atmosphere, differing in density and density (Fig. 1).

Troposphere

Troposphere- the lowest layer of the atmosphere, whose thickness above the poles is 8-10 km, in temperate latitudes - 10-12 km, and above the equator - 16-18 km.

Rice. 1. The structure of the Earth's atmosphere

The air in the troposphere is heated from the earth's surface, i.e. from land and water. Therefore, the air temperature in this layer decreases with height by an average of 0.6 °C for every 100 m. At the upper boundary of the troposphere, it reaches -55 °C. At the same time, in the region of the equator at the upper boundary of the troposphere, the air temperature is -70 °С, and in the region of the North Pole -65 °С.

About 80% of the mass of the atmosphere is concentrated in the troposphere, almost all water vapor is located, thunderstorms, storms, clouds and precipitation occur, and vertical (convection) and horizontal (wind) air movement occurs.

We can say that the weather is mainly formed in the troposphere.

Stratosphere

Stratosphere- the layer of the atmosphere located above the troposphere at an altitude of 8 to 50 km. The color of the sky in this layer appears purple, which is explained by the rarefaction of the air, due to which the sun's rays almost do not scatter.

The stratosphere contains 20% of the mass of the atmosphere. The air in this layer is rarefied, there is practically no water vapor, and therefore clouds and precipitation are almost not formed. However, stable air currents are observed in the stratosphere, the speed of which reaches 300 km / h.

This layer is concentrated ozone(ozone screen, ozonosphere), a layer that absorbs ultraviolet rays, preventing them from passing to the Earth and thereby protecting living organisms on our planet. Due to ozone, the air temperature at the upper boundary of the stratosphere is in the range from -50 to 4-55 °C.

Between the mesosphere and the stratosphere there is a transitional zone - the stratopause.

Mesosphere

Mesosphere- a layer of the atmosphere located at an altitude of 50-80 km. The air density here is 200 times less than at the surface of the Earth. The color of the sky in the mesosphere appears black, stars are visible during the day. The air temperature drops to -75 (-90)°С.

At an altitude of 80 km begins thermosphere. The air temperature in this layer rises sharply to a height of 250 m, and then becomes constant: at a height of 150 km it reaches 220-240 °C; at an altitude of 500-600 km it exceeds 1500 °C.

In the mesosphere and thermosphere, under the action of cosmic rays, gas molecules break up into charged (ionized) particles of atoms, so this part of the atmosphere is called ionosphere- a layer of very rarefied air, located at an altitude of 50 to 1000 km, consisting mainly of ionized oxygen atoms, nitric oxide molecules and free electrons. This layer is characterized by high electrification, and long and medium radio waves are reflected from it, as from a mirror.

In the ionosphere, auroras arise - the glow of rarefied gases under the influence of electrically charged particles flying from the Sun - and sharp fluctuations in the magnetic field are observed.

Exosphere

Exosphere- the outer layer of the atmosphere, located above 1000 km. This layer is also called the scattering sphere, since gas particles move here at high speed and can be scattered into outer space.

Composition of the atmosphere

The atmosphere is a mixture of gases consisting of nitrogen (78.08%), oxygen (20.95%), carbon dioxide (0.03%), argon (0.93%), a small amount of helium, neon, xenon, krypton (0.01%), ozone and other gases, but their content is negligible (Table 1). The modern composition of the Earth's air was established more than a hundred million years ago, but the sharply increased production activity man nevertheless led to his change. Currently, there is an increase in the content of CO 2 by about 10-12%.

The gases that make up the atmosphere perform various functional roles. However, the main significance of these gases is determined primarily by the fact that they very strongly absorb radiant energy and thus have a significant effect on the temperature regime of the Earth's surface and atmosphere.

Table 1. Chemical composition of dry atmospheric air at the earth's surface

Nitrogen, the most common gas in the atmosphere, chemically little active.

Oxygen, unlike nitrogen, is a chemically very active element. The specific function of oxygen is the oxidation of organic matter of heterotrophic organisms, rocks, and incompletely oxidized gases emitted into the atmosphere by volcanoes. Without oxygen, there would be no decomposition of dead organic matter.

The role of carbon dioxide in the atmosphere is exceptionally great. It enters the atmosphere as a result of the processes of combustion, respiration of living organisms, decay and is, first of all, the main building material for the creation of organic matter during photosynthesis. In addition, the property of carbon dioxide to transmit short-wave solar radiation and absorb part of thermal long-wave radiation is of great importance, which will create the so-called greenhouse effect, which will be discussed below.

The influence on atmospheric processes, especially on the thermal regime of the stratosphere, is also exerted by ozone. This gas serves as a natural absorber of solar ultraviolet radiation, and the absorption of solar radiation leads to air heating. The average monthly values ​​of the total ozone content in the atmosphere vary depending on the latitude of the area and the season within 0.23-0.52 cm (this is the thickness of the ozone layer at ground pressure and temperature). There is an increase in the ozone content from the equator to the poles and an annual variation with a minimum in autumn and a maximum in spring.

A characteristic property of the atmosphere can be called the fact that the content of the main gases (nitrogen, oxygen, argon) changes slightly with height: at an altitude of 65 km in the atmosphere, the nitrogen content is 86%, oxygen - 19, argon - 0.91, at an altitude of 95 km - nitrogen 77, oxygen - 21.3, argon - 0.82%. The constancy of the composition of atmospheric air vertically and horizontally is maintained by its mixing.

In addition to gases, air contains water vapor and solid particles. The latter can have both natural and artificial (anthropogenic) origin. These are flower pollen, tiny salt crystals, road dust, aerosol impurities. When the sun's rays penetrate the window, they can be seen with the naked eye.

There are especially many particulate matter in the air of cities and large industrial centers, where emissions of harmful gases and their impurities formed during fuel combustion are added to aerosols.

The concentration of aerosols in the atmosphere determines the transparency of the air, which affects the solar radiation reaching the Earth's surface. The largest aerosols are condensation nuclei (from lat. condensatio- compaction, thickening) - contribute to the transformation of water vapor into water droplets.

The value of water vapor is determined primarily by the fact that it delays the long-wave thermal radiation of the earth's surface; represents the main link of large and small moisture cycles; raises the temperature of the air when the water beds condense.

The amount of water vapor in the atmosphere varies over time and space. Thus, the concentration of water vapor near the earth's surface ranges from 3% in the tropics to 2-10 (15)% in Antarctica.

The average content of water vapor in the vertical column of the atmosphere in temperate latitudes is about 1.6-1.7 cm (the layer of condensed water vapor will have such a thickness). Information about water vapor in different layers of the atmosphere is contradictory. It was assumed, for example, that in the altitude range from 20 to 30 km, the specific humidity strongly increases with height. However, subsequent measurements indicate a greater dryness of the stratosphere. Apparently, the specific humidity in the stratosphere depends little on height and amounts to 2–4 mg/kg.

The variability of water vapor content in the troposphere is determined by the interaction of evaporation, condensation, and horizontal transport. As a result of the condensation of water vapor, clouds form and precipitation occurs in the form of rain, hail and snow.

The processes of phase transitions of water proceed mainly in the troposphere, which is why clouds in the stratosphere (at altitudes of 20-30 km) and mesosphere (near the mesopause), called mother-of-pearl and silver, are observed relatively rarely, while tropospheric clouds often cover about 50% of the entire earth surfaces.

The amount of water vapor that can be contained in the air depends on the temperature of the air.

1 m 3 of air at a temperature of -20 ° C can contain no more than 1 g of water; at 0 °C - no more than 5 g; at +10 °С - no more than 9 g; at +30 °С - no more than 30 g of water.

Conclusion: The higher the air temperature, the more water vapor it can contain.

Air can be rich and not saturated steam. So, if at a temperature of +30 ° C 1 m 3 of air contains 15 g of water vapor, the air is not saturated with water vapor; if 30 g - saturated.

Absolute humidity- this is the amount of water vapor contained in 1 m 3 of air. It is expressed in grams. For example, if they say "absolute humidity is 15", then this means that 1 mL contains 15 g of water vapor.

Relative humidity- this is the ratio (in percent) of the actual content of water vapor in 1 m 3 of air to the amount of water vapor that can be contained in 1 m L at a given temperature. For example, if a weather report is broadcast over the radio that the relative humidity is 70%, this means that the air contains 70% of the water vapor that it can hold at a given temperature.

The greater the relative humidity of the air, t. the closer the air is to saturation, the more likely it is to fall.

Always high (up to 90%) relative humidity is observed in the equatorial zone, since there is a high air temperature throughout the year and there is a large evaporation from the surface of the oceans. The same high relative humidity is in the polar regions, but only because at low temperatures even a small amount of water vapor makes the air saturated or close to saturation. In temperate latitudes, relative humidity varies seasonally - it is higher in winter and lower in summer.

The relative humidity of the air is especially low in deserts: 1 m 1 of air there contains two to three times less than the amount of water vapor possible at a given temperature.

To measure relative humidity, a hygrometer is used (from the Greek hygros - wet and metreco - I measure).

When cooled, saturated air cannot retain the same amount of water vapor in itself, it thickens (condenses), turning into droplets of fog. Fog can be observed in the summer on a clear cool night.

Clouds- this is the same fog, only it is formed not at the earth's surface, but at a certain height. As the air rises, it cools and the water vapor in it condenses. The resulting tiny droplets of water make up the clouds.

involved in the formation of clouds particulate matter suspended in the troposphere.

Clouds can have a different shape, which depends on the conditions of their formation (Table 14).

The lowest and heaviest clouds are stratus. They are located at an altitude of 2 km from the earth's surface. At an altitude of 2 to 8 km, more picturesque cumulus clouds can be observed. The highest and lightest are cirrus clouds. They are located at an altitude of 8 to 18 km above the earth's surface.

Atmospheric protection

The main sources are industrial enterprises and automobiles. In large cities, the problem of gas contamination of the main transport routes is very acute. That is why in many large cities of the world, including our country, environmental control car exhaust toxicity. According to experts, smoke and dust in the air can halve the flow of solar energy to the earth's surface, which will lead to a change in natural conditions.

ATMOSPHERE
gaseous envelope surrounding a celestial body. Its characteristics depend on the size, mass, temperature, rotation speed and chemical composition of a given celestial body, and are also determined by the history of its formation from the moment of its birth. Earth's atmosphere is made up of a mixture of gases called air. Its main constituents are nitrogen and oxygen in a ratio of approximately 4:1. A person is affected mainly by the state of the lower 15-25 km of the atmosphere, since it is in this lower layer that the bulk of the air is concentrated. The science that studies the atmosphere is called meteorology, although the subject of this science is also the weather and its effect on humans. The state of the upper layers of the atmosphere, located at altitudes from 60 to 300 and even 1000 km from the Earth's surface, is also changing. Strong winds, storms develop here, and such amazing electrical phenomena as auroras appear. Many of these phenomena are associated with fluxes of solar radiation, cosmic radiation, and the Earth's magnetic field. The high layers of the atmosphere are also a chemical laboratory, since there, under conditions close to vacuum, some atmospheric gases, under the influence of a powerful flow of solar energy, enter into chemical reactions. The science that studies these interrelated phenomena and processes is called the physics of the high layers of the atmosphere.
GENERAL CHARACTERISTICS OF THE EARTH'S ATMOSPHERE
Dimensions. Until sounding rockets and artificial satellites explored the outer layers of the atmosphere at distances several times greater than the radius of the Earth, it was believed that as you move away from the earth's surface, the atmosphere gradually becomes more rarefied and smoothly passes into interplanetary space. It has now been established that energy flows from the deep layers of the Sun penetrate into outer space far beyond the Earth's orbit, up to the outer limits of the Solar System. This so-called. sunny wind flows around the Earth's magnetic field, forming an elongated "cavity", inside which the Earth's atmosphere is concentrated. The Earth's magnetic field is noticeably narrowed on the day side facing the Sun and forms a long tongue, probably extending beyond the orbit of the Moon, on the opposite, night side. The boundary of the Earth's magnetic field is called the magnetopause. On the day side, this boundary passes at a distance of about seven Earth radii from the surface, but during periods of increased solar activity it is even closer to the Earth's surface. The magnetopause is also the boundary of the earth's atmosphere, the outer shell of which is also called the magnetosphere, since it contains charged particles (ions), whose movement is due to the earth's magnetic field. The total weight of atmospheric gases is approximately 4.5*1015 tons. Thus, the "weight" of the atmosphere per unit area, or atmospheric pressure, is approximately 11 tons/m2 at sea level.
Significance for life. It follows from the above that the Earth is separated from interplanetary space by a powerful protective layer. Outer space is permeated with powerful ultraviolet and X-ray radiation from the Sun and even harder cosmic radiation, and these types of radiation are detrimental to all living things. At the outer edge of the atmosphere, the radiation intensity is lethal, but a significant part of it is retained by the atmosphere far from the Earth's surface. The absorption of this radiation explains many properties of the high layers of the atmosphere, and especially the electrical phenomena that occur there. The lowest, surface layer of the atmosphere is especially important for a person who lives at the point of contact of the solid, liquid and gaseous shells of the Earth. The upper shell of the "solid" Earth is called the lithosphere. About 72% of the Earth's surface is covered by the waters of the oceans, which make up most of the hydrosphere. The atmosphere borders both the lithosphere and the hydrosphere. Man lives at the bottom of the air ocean and near or above the level of the water ocean. The interaction of these oceans is one of the important factors that determine the state of the atmosphere.
Compound. The lower layers of the atmosphere consist of a mixture of gases (see table). In addition to those listed in the table, other gases are also present in the form of small impurities in the air: ozone, methane, substances such as carbon monoxide (CO), nitrogen and sulfur oxides, ammonia.

COMPOSITION OF THE ATMOSPHERE

At sea level 1013.25 hPa (about 760 mmHg). The average global air temperature at the Earth's surface is 15°C, while the temperature varies from about 57°C in subtropical deserts to -89°C in Antarctica. Air density and pressure decrease with height according to a law close to exponential.

The structure of the atmosphere. Vertically, the atmosphere has a layered structure, determined mainly by the features of the vertical temperature distribution (figure), which depends on the geographical location, season, time of day, and so on. The lower layer of the atmosphere - the troposphere - is characterized by a drop in temperature with height (by about 6 ° C per 1 km), its height is from 8-10 km in polar latitudes to 16-18 km in the tropics. Due to the rapid decrease in air density with height, about 80% of the total mass of the atmosphere is in the troposphere. Above the troposphere is the stratosphere - a layer that is characterized in general by an increase in temperature with height. The transition layer between the troposphere and stratosphere is called the tropopause. In the lower stratosphere, up to a level of about 20 km, the temperature changes little with height (the so-called isothermal region) and often even slightly decreases. Higher, the temperature rises due to the absorption of solar UV radiation by ozone, slowly at first, and faster from a level of 34-36 km. The upper boundary of the stratosphere - the stratopause - is located at an altitude of 50-55 km, corresponding to the maximum temperature (260-270 K). The layer of the atmosphere, located at an altitude of 55-85 km, where the temperature again falls with height, is called the mesosphere, at its upper boundary - the mesopause - the temperature reaches 150-160 K in summer, and 200-230 K in winter. Above the mesopause, the thermosphere begins - a layer, characterized by a rapid increase in temperature, reaching values ​​of 800-1200 K at an altitude of 250 km. The corpuscular and X-ray radiation of the Sun is absorbed in the thermosphere, meteors are slowed down and burned out, so it performs the function of the Earth's protective layer. Even higher is the exosphere, from where atmospheric gases are dissipated into world space due to dissipation and where a gradual transition from the atmosphere to interplanetary space takes place.

Composition of the atmosphere. Up to an altitude of about 100 km, the atmosphere is practically homogeneous in chemical composition and the average molecular mass air (about 29) in it is constant. Near the Earth's surface, the atmosphere consists of nitrogen (about 78.1% by volume) and oxygen (about 20.9%), and also contains small amounts of argon, carbon dioxide (carbon dioxide), neon, and other constant and variable components (see Air ).

In addition, the atmosphere contains small amounts of ozone, nitrogen oxides, ammonia, radon, etc. The relative content of the main components of the air is constant over time and uniform in different geographical areas. The content of water vapor and ozone is variable in space and time; despite the low content, their role in atmospheric processes is very significant.

Above 100-110 km, the dissociation of oxygen, carbon dioxide and water vapor molecules occurs, so the molecular weight of air decreases. At an altitude of about 1000 km, light gases - helium and hydrogen - begin to predominate, and even higher, the Earth's atmosphere gradually turns into interplanetary gas.

The most important variable component of the atmosphere is water vapor, which enters the atmosphere through evaporation from the surface of water and moist soil, as well as through transpiration by plants. The relative content of water vapor varies near the earth's surface from 2.6% in the tropics to 0.2% in the polar latitudes. With height, it quickly falls, decreasing by half already at a height of 1.5-2 km. The vertical column of the atmosphere at temperate latitudes contains about 1.7 cm of the “precipitated water layer”. When water vapor condenses, clouds form, from which atmospheric precipitation falls in the form of rain, hail, and snow.

An important component of atmospheric air is ozone, 90% concentrated in the stratosphere (between 10 and 50 km), about 10% of it is in the troposphere. Ozone provides absorption of hard UV radiation (with a wavelength of less than 290 nm), and this is its protective role for the biosphere. The values ​​of the total ozone content vary depending on the latitude and season, ranging from 0.22 to 0.45 cm (the thickness of the ozone layer at a pressure of p= 1 atm and a temperature of T = 0°C). AT ozone holes, observed in the spring in Antarctica since the early 1980s, the ozone content can drop to 0.07 cm. latitudes. An essential variable component of the atmosphere is carbon dioxide, the content of which in the atmosphere has increased by 35% over the past 200 years, which is mainly explained by the anthropogenic factor. Its latitudinal and seasonal variability associated with plant photosynthesis and solubility in sea ​​water(according to Henry's law, the solubility of a gas in water decreases with increasing temperature).

An important role in the formation of the planet's climate is played by atmospheric aerosol - solid and liquid particles suspended in the air ranging in size from several nm to tens of microns. There are aerosols of natural and anthropogenic origin. Aerosol is formed in the process of gas-phase reactions from the products of plant life and human economic activity, volcanic eruptions, as a result of dust being lifted by the wind from the surface of the planet, especially from its desert regions, and is also formed from cosmic dust entering the upper atmosphere. Most of the aerosol is concentrated in the troposphere; aerosol from volcanic eruptions forms the so-called Junge layer at an altitude of about 20 km. The largest amount of anthropogenic aerosol enters the atmosphere as a result of the operation of vehicles and thermal power plants, chemical industries, fuel combustion, etc. Therefore, in some areas the composition of the atmosphere differs markedly from ordinary air, which required the creation of a special service for monitoring and controlling the level of atmospheric air pollution.

Atmospheric evolution. The modern atmosphere seems to be of secondary origin: it was formed from gases released by the solid shell of the Earth after the formation of the planet was completed about 4.5 billion years ago. During the geological history of the Earth, the atmosphere has undergone significant changes in its composition under the influence of a number of factors: dissipation (volatilization) of gases, mainly lighter ones, into outer space; release of gases from the lithosphere as a result of volcanic activity; chemical reactions between the components of the atmosphere and the rocks that make up the earth's crust; photochemical reactions in the atmosphere itself under the influence of solar UV radiation; accretion (capture) of the matter of the interplanetary medium (for example, meteoric matter). The development of the atmosphere is closely connected with geological and geochemical processes, and for the last 3-4 billion years also with the activity of the biosphere. A significant part of the gases that make up the modern atmosphere (nitrogen, carbon dioxide, water vapor) arose during volcanic activity and intrusion, which carried them out of the depths of the Earth. Oxygen appeared in appreciable quantities about 2 billion years ago as a result of the activity of photosynthetic organisms that originally originated in the surface waters of the ocean.

Based on the data on the chemical composition of carbonate deposits, estimates of the amount of carbon dioxide and oxygen in the atmosphere of the geological past were obtained. Throughout the Phanerozoic (the last 570 million years of Earth's history), the amount of carbon dioxide in the atmosphere varied widely, in accordance with the level of volcanic activity, ocean temperature, and photosynthesis. Most of this time, the concentration of carbon dioxide in the atmosphere was significantly higher than the current one (up to 10 times). The amount of oxygen in the atmosphere of the Phanerozoic changed significantly, and the tendency to increase it prevailed. In the Precambrian atmosphere, the mass of carbon dioxide was, as a rule, greater, and the mass of oxygen, less than in the atmosphere of the Phanerozoic. Fluctuations in the amount of carbon dioxide have had a significant impact on the climate in the past, increasing the greenhouse effect with an increase in the concentration of carbon dioxide, due to which the climate during the main part of the Phanerozoic was much warmer than in the modern era.

atmosphere and life. Without an atmosphere, Earth would be a dead planet. Organic life proceeds in close interaction with the atmosphere and its associated climate and weather. Insignificant in mass compared to the planet as a whole (about a millionth part), the atmosphere is a sine qua non for all life forms. Oxygen, nitrogen, water vapor, carbon dioxide, and ozone are the most important atmospheric gases for the life of organisms. When carbon dioxide is absorbed by photosynthetic plants, organic matter is created that is used as an energy source by the vast majority of living beings, including humans. Oxygen is necessary for the existence of aerobic organisms, for which the energy supply is provided by the oxidation reactions of organic matter. Nitrogen, assimilated by some microorganisms (nitrogen fixers), is necessary for the mineral nutrition of plants. Ozone, which absorbs the Sun's harsh UV radiation, significantly attenuates this life-threatening portion of the sun's radiation. Condensation of water vapor in the atmosphere, the formation of clouds and the subsequent precipitation of precipitation supply water to land, without which no form of life is possible. The vital activity of organisms in the hydrosphere is largely determined by the amount and chemical composition of atmospheric gases dissolved in water. Since the chemical composition of the atmosphere significantly depends on the activity of organisms, the biosphere and atmosphere can be considered as part of a single system, the maintenance and evolution of which (see Biogeochemical cycles) was of great importance for changing the composition of the atmosphere throughout the history of the Earth as a planet.

Radiation, heat and water balances of the atmosphere. Solar radiation is practically the only source of energy for all physical processes in the atmosphere. The main feature of the radiation regime of the atmosphere is the so-called greenhouse effect: the atmosphere transmits solar radiation to the earth's surface quite well, but actively absorbs the thermal long-wave radiation of the earth's surface, part of which returns to the surface in the form of counter radiation that compensates for the radiative heat loss of the earth's surface (see Atmospheric radiation ). In the absence of an atmosphere, the average temperature of the earth's surface would be -18°C, in reality it is 15°C. Incoming solar radiation is partially (about 20%) absorbed into the atmosphere (mainly by water vapor, water droplets, carbon dioxide, ozone and aerosols), and is also scattered (about 7%) by aerosol particles and density fluctuations (Rayleigh scattering). The total radiation, reaching the earth's surface, is partially (about 23%) reflected from it. The reflectance is determined by the reflectivity of the underlying surface, the so-called albedo. On average, the Earth's albedo for the integral solar radiation flux is close to 30%. It varies from a few percent (dry soil and black soil) to 70-90% for freshly fallen snow. The radiative heat exchange between the earth's surface and the atmosphere essentially depends on the albedo and is determined by the effective radiation of the earth's surface and the counter-radiation of the atmosphere absorbed by it. The algebraic sum of radiation fluxes entering the earth's atmosphere from outer space and leaving it back is called the radiation balance.

Transformations of solar radiation after its absorption by the atmosphere and the earth's surface determine the heat balance of the Earth as a planet. The main source of heat for the atmosphere is the earth's surface; heat from it is transferred not only in the form of long-wave radiation, but also by convection, and is also released during the condensation of water vapor. The shares of these heat inflows are on average 20%, 7% and 23%, respectively. About 20% of heat is also added here due to the absorption of direct solar radiation. The flux of solar radiation per unit of time through a single area perpendicular to the sun's rays and located outside the atmosphere at an average distance from the Earth to the Sun (the so-called solar constant) is 1367 W / m 2, the changes are 1-2 W / m 2 depending on cycle of solar activity. With a planetary albedo of about 30%, the time-average global influx of solar energy to the planet is 239 W/m 2 . Since the Earth as a planet emits the same amount of energy into space on average, then, according to the Stefan-Boltzmann law, the effective temperature of the outgoing thermal long-wave radiation is 255 K (-18°C). At the same time, the average temperature of the earth's surface is 15°C. The 33°C difference is due to the greenhouse effect.

The water balance of the atmosphere as a whole corresponds to the equality of the amount of moisture evaporated from the surface of the Earth, the amount of precipitation falling on the earth's surface. The atmosphere over the oceans receives more moisture from evaporation processes than over land, and loses 90% in the form of precipitation. Excess water vapor over the oceans is carried to the continents by air currents. The amount of water vapor transported into the atmosphere from the oceans to the continents is equal to the volume of river flow that flows into the oceans.

air movement. The Earth has a spherical shape, so much less solar radiation comes to its high latitudes than to the tropics. As a result, large temperature contrasts arise between latitudes. The relative position of the oceans and continents also significantly affects the distribution of temperature. Due to the large mass of ocean waters and the high heat capacity of water, seasonal fluctuations in ocean surface temperature are much less than those of land. In this regard, in the middle and high latitudes, the air temperature over the oceans is noticeably lower in summer than over the continents, and higher in winter.

The uneven heating of the atmosphere in different regions of the globe causes a distribution of atmospheric pressure that is not uniform in space. At sea level, the pressure distribution is characterized by relatively low values ​​near the equator, an increase in the subtropics (high pressure belts), and a decrease in middle and high latitudes. At the same time, over the continents of extratropical latitudes, the pressure is usually increased in winter, and lowered in summer, which is associated with the temperature distribution. Under the action of a pressure gradient, the air experiences an acceleration directed from areas of high pressure to areas of low pressure, which leads to the movement of air masses. The moving air masses are also affected by the deflecting force of the Earth's rotation (the Coriolis force), the friction force, which decreases with height, and in the case of curvilinear trajectories, the centrifugal force. Of great importance is the turbulent mixing of air (see Turbulence in the atmosphere).

A complex system of air currents (general circulation of the atmosphere) is associated with the planetary distribution of pressure. In the meridional plane, on average, two or three meridional circulation cells are traced. Near the equator, heated air rises and falls in the subtropics, forming a Hadley cell. The air of the reverse Ferrell cell also descends there. At high latitudes, a direct polar cell is often traced. Meridional circulation velocities are on the order of 1 m/s or less. Due to the action of the Coriolis force, westerly winds are observed in most of the atmosphere with speeds in the middle troposphere of about 15 m/s. There are relatively stable wind systems. These include trade winds - winds blowing from high pressure belts in the subtropics to the equator with a noticeable eastern component (from east to west). Monsoons are quite stable - air currents that have a clearly pronounced seasonal character: they blow from the ocean to the mainland in summer and in the opposite direction in winter. The monsoons of the Indian Ocean are especially regular. In middle latitudes, the movement of air masses is mainly western (from west to east). This is a zone of atmospheric fronts, on which large eddies arise - cyclones and anticyclones, covering many hundreds and even thousands of kilometers. Cyclones also occur in the tropics; here they differ in smaller sizes, but very high wind speeds, reaching hurricane force (33 m/s or more), the so-called tropical cyclones. In the Atlantic and eastern Pacific they are called hurricanes, and in the western Pacific they are called typhoons. In the upper troposphere and lower stratosphere, in the areas separating the direct cell of the meridional Hadley circulation and the reverse Ferrell cell, relatively narrow, hundreds of kilometers wide, jet streams with sharply defined boundaries are often observed, within which the wind reaches 100-150 and even 200 m/ With.

Climate and weather. The difference in the amount of solar radiation coming at different latitudes to the earth's surface, which is diverse in physical properties, determines the diversity of the Earth's climates. From the equator to tropical latitudes, the air temperature near the earth's surface averages 25-30 ° C and changes little during the year. In the equatorial zone, a lot of precipitation usually falls, which creates conditions for excessive moisture there. In tropical zones, the amount of precipitation decreases and in some areas becomes very small. Here are the vast deserts of the Earth.

In subtropical and middle latitudes, air temperature varies significantly throughout the year, and the difference between summer and winter temperatures is especially large in areas of the continents remote from the oceans. Thus, in some areas of Eastern Siberia, the annual amplitude of air temperature reaches 65°С. Humidification conditions in these latitudes are very diverse, depend mainly on the regime of the general circulation of the atmosphere, and vary significantly from year to year.

In the polar latitudes, the temperature remains low throughout the year, even if there is a noticeable seasonal variation. This contributes to the widespread distribution of ice cover on the oceans and land and permafrost, occupying over 65% of Russia's area, mainly in Siberia.

Over the past decades, changes in the global climate have become more and more noticeable. The temperature rises more at high latitudes than at low latitudes; more in winter than in summer; more at night than during the day. Over the 20th century, the average annual air temperature near the earth's surface in Russia increased by 1.5-2 ° C, and in some regions of Siberia an increase of several degrees is observed. This is associated with an increase in the greenhouse effect due to an increase in the concentration of small gaseous impurities.

The weather is determined by the conditions of atmospheric circulation and the geographical location of the area, it is most stable in the tropics and most changeable in the middle and high latitudes. Most of all, the weather changes in the zones of change of air masses, due to the passage of atmospheric fronts, cyclones and anticyclones, carrying precipitation and increasing wind. Data for weather forecasting is collected from ground-based weather stations, ships and aircraft, and meteorological satellites. See also meteorology.

Optical, acoustic and electrical phenomena in the atmosphere. When electromagnetic radiation propagates in the atmosphere, as a result of refraction, absorption and scattering of light by air and various particles (aerosol, ice crystals, water drops), various optical phenomena arise: rainbow, crowns, halo, mirage, etc. Light scattering determines the apparent height of the firmament and blue color of the sky. The visibility range of objects is determined by the conditions of light propagation in the atmosphere (see Atmospheric visibility). The transparency of the atmosphere at different wavelengths determines the communication range and the possibility of detecting objects with instruments, including the possibility of astronomical observations from the Earth's surface. For studies of optical inhomogeneities in the stratosphere and mesosphere, the phenomenon of twilight plays an important role. For example, photographing twilight with spacecraft allows detection of aerosol layers. Features of the propagation of electromagnetic radiation in the atmosphere determine the accuracy of methods for remote sensing of its parameters. All these questions, like many others, are studied by atmospheric optics. Refraction and scattering of radio waves determine the possibilities of radio reception (see Propagation of radio waves).

The propagation of sound in the atmosphere depends on the spatial distribution of temperature and wind speed (see Atmospheric acoustics). It is of interest for remote sensing of the atmosphere. Explosions of charges launched by rockets in upper atmosphere, gave a wealth of information about wind systems and the course of temperature in the stratosphere and mesosphere. In a stably stratified atmosphere, when the temperature falls with height more slowly than the adiabatic gradient (9.8 K/km), so-called internal waves arise. These waves can propagate upward into the stratosphere and even into the mesosphere, where they attenuate, contributing to increased wind and turbulence.

The negative charge of the Earth and the electric field caused by it, the atmosphere, together with the electrically charged ionosphere and magnetosphere, create a global electrical circuit. An important role is played by the formation of clouds and lightning electricity. The danger of lightning discharges necessitated the development of methods for lightning protection of buildings, structures, power lines and communications. This phenomenon is of particular danger to aviation. Lightning discharges cause atmospheric radio interference, called atmospherics (see Whistling atmospherics). During a sharp increase in the strength of the electric field, luminous discharges are observed that arise on the points and sharp corners of objects protruding above the earth's surface, on individual peaks in the mountains, etc. (Elma lights). The atmosphere always contains a number of light and heavy ions, which vary greatly depending on the specific conditions, which determine the electrical conductivity of the atmosphere. The main air ionizers near the earth's surface are the radiation of radioactive substances contained in the earth's crust and in the atmosphere, as well as cosmic rays. See also atmospheric electricity.

Human influence on the atmosphere. Over the past centuries, there has been an increase in the concentration of greenhouse gases in the atmosphere due to human activities. Percentage carbon dioxide increased from 2.8-10 2 two hundred years ago to 3.8-10 2 in 2005, methane content - from 0.7-10 1 about 300-400 years ago to 1.8-10 -4 21st century; about 20% of the increase in the greenhouse effect over the past century was given by freons, which practically did not exist in the atmosphere until the middle of the 20th century. These substances are recognized as stratospheric ozone depleters and their production is prohibited by the 1987 Montreal Protocol. The increase in carbon dioxide concentration in the atmosphere is caused by the burning of ever-increasing amounts of coal, oil, gas and other carbon fuels, as well as the deforestation, resulting in a decrease in the absorption of carbon dioxide through photosynthesis. The concentration of methane increases with the growth of oil and gas production (due to its losses), as well as with the expansion of rice crops and an increase in the number of cattle. All this contributes to climate warming.

To change the weather, methods of active influence on atmospheric processes have been developed. They are used to protect agricultural plants from hail damage by dispersing special reagents in thunderclouds. There are also methods for dispelling fog at airports, protecting plants from frost, influencing clouds to increase rainfall in the right places, or to disperse clouds during public events.

Study of the atmosphere. Information about the physical processes in the atmosphere is obtained primarily from meteorological observations, which are carried out by a global network of permanent meteorological stations and posts located on all continents and on many islands. Daily observations provide information about air temperature and humidity, atmospheric pressure and precipitation, cloudiness, wind, etc. Observations of solar radiation and its transformations are carried out at actinometric stations. Of great importance for the study of the atmosphere are the networks of aerological stations, where meteorological measurements are made with the help of radiosondes up to a height of 30-35 km. At a number of stations, observations are made of atmospheric ozone, electrical phenomena in the atmosphere, and the chemical composition of the air.

Data from ground stations are supplemented by observations on the oceans, where "weather ships" operate, permanently located in certain areas of the World Ocean, as well as meteorological information received from research and other ships.

In recent decades, an increasing amount of information about the atmosphere has been obtained with the help of meteorological satellites, on which instruments are installed for photographing clouds and measuring the fluxes of ultraviolet, infrared, and microwave radiation from the Sun. Satellites make it possible to obtain information about vertical temperature profiles, cloudiness and its water content, elements of the atmospheric radiation balance, ocean surface temperature, etc. Using measurements of the refraction of radio signals from a system of navigation satellites, it is possible to determine vertical profiles of density, pressure and temperature, as well as moisture content in the atmosphere . With the help of satellites, it became possible to clarify the value of the solar constant and planetary albedo of the Earth, build maps of the radiation balance of the Earth-atmosphere system, measure the content and variability of small atmospheric impurities, and solve many other problems of atmospheric physics and environmental monitoring.

Lit .: Budyko M. I. Climate in the past and future. L., 1980; Matveev L. T. Course of general meteorology. Physics of the atmosphere. 2nd ed. L., 1984; Budyko M. I., Ronov A. B., Yanshin A. L. History of the atmosphere. L., 1985; Khrgian A.Kh. Atmospheric Physics. M., 1986; Atmosphere: A Handbook. L., 1991; Khromov S. P., Petrosyants M. A. Meteorology and climatology. 5th ed. M., 2001.

G. S. Golitsyn, N. A. Zaitseva.

The formation of the Earth's atmosphere began in ancient times - in the protoplanetary stage of the Earth's development, during the active period with the release of a huge amount of gases. Later, when the biosphere appeared on Earth, the formation of the atmosphere continued due to gas exchange between water, plants, animals and their decomposition products.

Throughout geological history, the Earth's atmosphere has undergone a series of profound transformations.

Earth's primary atmosphere. Recovery.

Part Earth's primary atmosphere at the protoplanetary stage of the development of the Earth (more than 4.2 billion years ago), methane, ammonia, and carbon dioxide were predominantly included. Then, as a result of degassing and continuous weathering processes on the earth's surface, the composition of the Earth's primary atmosphere was enriched with water vapor, carbon compounds (CO 2, CO) and sulfur, as well as strong halogen acids (HCI, HF, HI) and boric acid. The initial atmosphere was very thin.

Earth's secondary atmosphere. Oxidative.

Subsequently, the primary atmosphere began to transform into a secondary one. This happened as a result of the same weathering processes that took place on the surface of the earth, volcanic and solar activity, as well as due to the vital activity of cyanobacteria and blue-green algae.

The result of the transformation was the decomposition of methane into hydrogen and carbon dioxide, ammonia - into nitrogen and hydrogen. Carbon dioxide and nitrogen began to accumulate in the Earth's atmosphere.

Blue-green algae through photosynthesis began to produce oxygen, which was almost all spent on the oxidation of other gases and rocks. As a result, ammonia was oxidized to molecular nitrogen, methane and carbon monoxide - to carbon dioxide, sulfur and hydrogen sulfide - to SO 2 and SO 3.

Thus, the atmosphere gradually turned from a reducing atmosphere into an oxidizing one.

Formation and evolution of carbon dioxide in the primary and secondary atmosphere.

Sources of carbon dioxide in the early stages of atmospheric formation:

• Methane oxidation,
• Degassing of the Earth's mantle,
• Weathering of rocks.

At the turn of the Proterozoic and Paleozoic (about 600 million years ago), the content of carbon dioxide in the atmosphere decreased and amounted to only tenths of a percent of the total volume of gases in the atmosphere.

The current level of carbon dioxide content in the atmosphere reached only 10-20 million years ago.

Formation and evolution of oxygen in the primary and secondary atmosphere.

Sources of oxygen early stages of atmospheric formation :

• Degassing of the Earth's mantle - almost all oxygen was spent on oxidative processes.
• Photodissociation of water (decomposition into hydrogen and oxygen molecules) in the atmosphere under the action of ultraviolet radiation - as a result, free oxygen molecules appeared in the atmosphere.
• Processing of carbon dioxide into oxygen by eukaryotes. The appearance of free oxygen in the atmosphere led to the death of prokaryotes (adapted to life in reducing conditions) and the emergence of eukaryotes (adapted to live in an oxidizing environment).

Change in the concentration of oxygen in the atmosphere.

Archean - first half of the Proterozoic - oxygen concentration 0.01% of the current level (Urey point). Almost all of the resulting oxygen was spent on the oxidation of iron and sulfur. This continued until all the ferrous iron on the surface of the earth was oxidized. Since then, oxygen began to accumulate in the atmosphere.

The second half of the Proterozoic - the end of the early Vendian - the concentration of oxygen in the atmosphere is 0.1% of the current level (Pasteur point).

Late Vendian - Silurian period. Free oxygen stimulated the development of life - the anaerobic fermentation process was replaced by an energetically more promising and progressive oxygen metabolism. Since then, the accumulation of oxygen in the atmosphere has been quite fast. The emergence of plants from the sea to land (450 million years ago) led to the stabilization of the oxygen level in the atmosphere.

Mid Cretaceous . The final stabilization of the oxygen concentration in the atmosphere is associated with the appearance of flowering plants (100 million years ago).

Formation and evolution of nitrogen in the primary and secondary atmosphere.

Nitrogen was formed in the early stages of the development of the Earth due to the decomposition of ammonia. The binding of atmospheric nitrogen and its burial in marine sediments began with the advent of organisms. After the release of living organisms on land, nitrogen began to be buried in continental sediments. The process of nitrogen fixation was especially intensified with the advent of terrestrial plants.

Thus, the composition of the Earth's atmosphere determined the characteristics of the life of organisms, contributed to their evolution, development and settlement on the surface of the earth. But in the history of the Earth there were sometimes failures in the distribution of the gas composition. The reason for this was various catastrophes that occurred more than once during the Cryptozoic and Phanerozoic. These failures led to mass extinctions of the organic world.

The composition of the ancient and modern atmosphere in percentage terms is shown in Table 1.

Table 1. Composition of the Earth's primary and modern atmosphere.